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The Difference Between Nylon 6.6 and Nylon 6

Author: Harry

Jan. 13, 2025

Understanding the Distinction Between Nylon 6.6 and Nylon 6

Nylon is categorized into various types of polymers, each exhibiting unique traits. While all nylons possess common features, differences exist among them, particularly between Nylon 6.6 and Nylon 6. These two variants frequently surface in industrial sewing and thread applications, and it is essential to understand their unique properties to make the best choice for your needs.

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Chemical Composition and Characteristics

In chemical terms, Nylon 6 is derived from a single monomer containing 6 carbon atoms. Conversely, Nylon 6.6 comprises two separate monomers, each with 6 carbon atoms, leading to its name.

Both materials are noted for their resilience to high temperature and their overall toughness. Yet, when evaluating their specific attributes, their distinctions become evident.

Nylon 6 Characteristics

Nylon 6 exemplifies the core qualities of the nylon category, offering hardness, stiffness, and durability. It showcases commendable mechanical damping and insulation properties.

Nylon 6 excels in its low-friction sliding capabilities, demonstrating exceptional wear resistance and fatigue durability. Moreover, it is easy to machine and can be formed into various designs with a stunning finish.

Nylon 6.6 Characteristics

While Nylon 6.6 shares similarities with Nylon 6, it stands out with a higher melting point. For instance, at a temperature of 160 degrees Celsius, Nylon 6.6 exhibits a heat age strength at break of 13.6 kg, in contrast to Nylon 6's 12.0 kg.

As the temperature escalates to 180 degrees, the disparity widens: Nylon 6.6 maintains its heat age strength at 11.5 kg, while Nylon 6 plummets to 2.6 kg, which can significantly influence specific applications.

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Certain industrial processes, such as tire cord manufacturing, utilize heat to embed the fiber into the final product. Nylon 6.6 adeptly endures these processes, maintaining its strength over time, while Nylon 6 tends to degrade or disrupt the manufacturing flow, impacting productivity.

Nylon 6.6 is recognized for its low creep rates, excellent stretch recovery, and heightened abrasion resistance compared to Nylon 6. The fibers of Nylon 6.6 are derived from a material that is 33% more resistant to abrasion than Nylon 6, enduring up to 60,000 cycles compared to Nylon 6's 40,000 cycles. This feature is pivotal for demanding industrial applications demanding long-lasting performance.

Applications of Nylon 6.6

Nylon 6.6 serves numerous roles, ranging from micro denier to heavy denier and high-tech applications. In its micro denier form, it is predominantly utilized in apparel due to its durability and resistance to wear, making it suitable for high-performance sportswear and industrial work attire.

The heavy denier variant finds its application in various industrial products and tires. In high-tech constructions, Nylon 6.6 is present in items such as automotive airbags and parachutes, where performance and reliability are crucial.

Applications of Nylon 6

The primary application of Nylon 6 lies within industrial yarn, encompassing cords, resilient fabrics, toothbrush bristles, and other products requiring resilience coupled with flexibility.

Nylon 6 can also be found in textiles with a desirable sheen, such as hosiery and chiffon, thanks to its gleaming surface quality.

Comparison Summary

In order to clarify the differences between Nylon 6.6 and Nylon 6, we have created a comparative table. On one side, observe Nylon 6; on the opposite side, see Nylon 6.6 for a detailed contrast.

For further discussion on your specifications regarding nylon 66 yarn, please reach out to our knowledgeable sales team to discover the best solutions tailored for your requirements.

Nylon 6 and Nylon 66 Yarn

Nylon Overview
Nylon is renowned as the first synthetic fiber to be commercialized, conceived by scientists at Du Pont in the 1930s, led by American chemist Wallace Hume Caruthers. This polyamide fiber, stemming from both a diamine and a dicarboxylic acid, invites considerable diversity in its chemical composition, resulting in multiple nylon fiber types. Among the various forms of nylon, Nylon 66 (polyhexamethylene adiamide) and Nylon 6 (Polycaprolactam) emerge as the most widely utilized. The former finds favor within North American markets while the latter holds greater appeal in Europe and other regions. The presence of the amide group (-CO-NH-) promotes hydrogen bonding between polyamide chains, endowing nylon with impressive strength under high temperatures, toughness in colder conditions, and excellent characteristics like stiffness, wear and abrasion resistance, low friction, and strong chemical resistance. Collectively, these attributes have categorized nylons among the most robust synthetic fibers in prevalent use, rendering them vital engineering thermoplastics. Properties of Nylon Fabrics
Strength: Nylon fibers exhibit outstanding tenacity, maintaining their strength over time. With a favorable strength-to-weight ratio, nylon represents one of the lightest, most robust textile fibers suitable for workload-intensive areas such as jeans and socks. Its abrasion resistance is exceptional. Elasticity: Thanks to good elasticity, nylon is ideal for apparel. The ability to return to its original length without retaining wrinkles or creases enhances its functionality. However, excessive stretching may hinder total shape recovery. Resilience: Nylon fabrics demonstrate remarkable resilience, maintaining a smooth appearance, with easy removal of day-to-day wrinkles. Drapability: Fabrics crafted from nylon filament yarn showcase excellent draping attributes. Different yarn sizes yield versatile drape quality, making lightweight nylon nightgowns exhibit superior draping alongside medium-weight dress fabrics. Heat Conductivity: The heat conductivity of nylon fabrics varies based on construction style, such as staple or filament types used, yielding cooler surfaces in open constructions as opposed to closed ones. Absorbency: Nylon fabrics exhibit low absorbency, which has both advantages (such as quick-drying properties) and disadvantages (like discomfort in warm, humid conditions). Cleanliness and Washability: Nylon garments are low-maintenance, characterized by smooth, non-absorbent properties that prevent dirt accumulation, making them easily washable even with a damp cloth. Effect of Bleaches: Generally, nylon fabrics maintain their whiteness without the need for bleaching, but oxidizing bleaches like hydrogen peroxide may be necessary for those with discoloration. Shrinkage: After washing, nylon fabrics retain both their shape and appearance, exhibiting excellent stability and minimal shrinkage. Effect of Heat: Low-temperature ironing is advisable, as high temperatures can cause glazing and melting. Effect of Light: Resistance to sunlight is low, making nylon fabrics unsuitable for curtains, as they weaken upon prolonged exposure. Resistance to Insects: Nylon displays resilience against moths and fungi. Reaction to Alkalis: While alkalis typically pose little risk, exposure to them can weaken nylon fibers over time. Reaction to Acids: Nylon's resilience decreases against strong acids. Affinity for Dyes: The material readily accepts a vast range of dyes, ensuring vibrant colors with good fading resistance. Resistance to Perspiration: Finally, nylon fabrics resist perspiration effects well.

Nylon 66 Yarn Features

Nylon 66 filament yarn excels in clothing applications, encompassing weaving and circular knitting. Its fabric properties include:
  • Enhanced toughness due to a higher yarn modulus.
  • Superior drape quality and softness.
  • Resistance to crinkling, aided by its elastic recovery.
  • Stable measurements and high strength, leading to less brittleness in cold weather.
  • Great abrasion resistance and less discoloration due to heat.
  • Effective moisture absorption, ventilation, and quick-drying properties.
Applications:
Underwear, lingerie, pantyhose, fashion garments, fitness attire, sportswear, beach shorts, and casual jackets.

Nylon 6 Yarn Types

Nylon 6 yarn comes in five different categories:
  • High-Oriented Nylon Yarn (HOY): Highly appealing and softer, suitable for clothing and various industrial applications.
  • Fully Drawn Nylon Yarn (FDY): Primarily used in clothing and industrial contexts.
  • Partially Oriented Nylon Yarn (POY): Designed for texturizing DTY.
  • Draw Textured Nylon Yarn (DTY): Utilized for various clothing functions including circular and warp knitting.
  • Air Textured Nylon Yarn (ATY): Known for its cotton-like feel, lightweight nature, and quick-drying ability, suitable for sportswear and casual clothing.
Overall, the critical difference between Nylon 6 and Nylon 6.6 resides in their melting points, with Nylon 6.6 demonstrating superior thermal stability, making it easier to manage during ironing and washing. General Care Tips for Nylon Fiber
  • Most nylon items can be washed in a machine and tumble dried on low heat. Utilize warm water with fabric softener during the final rinse.
  • Promptly remove items from the dryer once the cycle concludes.
  • If ironing is necessary, utilize a warm iron setting.
Nylon 6 yarn produced by Benlon India demonstrates exceptional resistance to light degradation. Furthermore, Nylon 6 yarn often exhibits advantages over Nylon 6.6 regarding dyeability, thermal stability, and elastic recovery, making it particularly ideal for textiles and carpets. Benlon India Ltd. supplies conventional dyed nylon yarn mainly to hosiery manufacturers. As a premium product, it caters to manufacturers of high-quality textile items. Custom-made yarn is also available for specific manufacturer needs, frequently used in the production of socks, sportswear, and name tapes.

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